Ring-opening reaction of 2,5-dioctyldithieno[2,3-b:3',2'-d]thiophene in the presence of aryllithium reagents

نویسندگان

  • Hao Zhong
  • Jianwu Shi
  • Jianxun Kang
  • Shaomin Wang
  • Xinming Liu
  • Hua Wang
چکیده

In this paper, the ring-opening reaction of 2,5-dioctyldithieno[2,3-b:3',2'-d]thiophene with aryllithium in THF at low temperature to generate 2'-arylthio-3,3'-bithiophene-2-carbaldehydes is studied. Nine examples are explored and all the products are characterized by (1)H NMR, (13)C NMR and HRMS. The relative relationship between the structures of aryl groups and the efficiency of ring-opening reactions are discussed.

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عنوان ژورنال:

دوره 9  شماره 

صفحات  -

تاریخ انتشار 2013